Near-field optical studies of local photomodification in nanostructured materials

J Microsc. 1999 May-Jun;194(Pt 2-3):574-7. doi: 10.1046/j.1365-2818.1999.00542.x.

Abstract

Fractal aggregates of silver nanoparticles are studied experimentally using atomic force microscopy and photon scanning tunnelling microscopy. Large changes in the near-field optical response of fractal aggregates are observed after the irradiation of samples with nanosecond laser pulses. The threshold energy density for photomodification using a 532 nm laser is measured to be 9 mJ cm(-2). It is shown that photomodification-induced changes in the local optical response can be two orders of magnitude larger than changes in far-field absorption.