Hydrogen-bonded supramolecular lattice of the 1:3:4 complex between [5,10,15,20-meso-tetrakis(4-hydroxyphenyl)porphyrinato-kappa(4)N]zinc(II), dibenzo-24-crown-8 and methanol

Acta Crystallogr C. 2002 Jun;58(Pt 6):m344-6. doi: 10.1107/s010827010200776x. Epub 2002 May 31.

Abstract

The title compound, [5,10,15,20-meso-tetrakis(4-hydroxyphenyl)porphyrinato-kappa(4)N]zinc(II) tris(dibenzo-24-crown-8) methanol tetrasolvate, [Zn(C(44)H(28)N(4)O(4))].3C(24)H(32)O(8).4CH(4)O, was synthesized and its molecular structure precisely characterized by low-temperature single-crystal analysis. All the components are involved in hydrogen bonding with each other, thus forming an extensively hydrogen-bonded supramolecular lattice. The functionalized porphyrin moiety coordinates both equatorially and axially to the neighboring species.