A novel scandium fluoride, [C2N2H10]0.5[ScF4], with an unprecedented tungsten bronze-related layer structure

Nicholas F Stephens; Alexandra M Z Slawin; Philip Lightfoot

doi:10.1039/b316312a

A novel scandium fluoride, [C2N2H10]0.5[ScF4], with an unprecedented tungsten bronze-related layer structure

Chem Commun (Camb). 2004 Mar 7:(5):614-5. doi: 10.1039/b316312a. Epub 2004 Feb 9.

Authors

Nicholas F Stephens¹, Alexandra M Z Slawin, Philip Lightfoot

Affiliation

¹ School of Chemistry, University of St Andrews, St Andrews, Fife, UK KY16 9ST.

PMID: 14973634
DOI: 10.1039/b316312a

Abstract

[C(2)N(2)H(10)](0.5)[ScF(4)] exhibits isolated anionic layers of corner-linked ScF(6) octahedra enclosing 3-, 4-, 5- and 6-membered rings, with features reminiscent of both hexagonal and tetragonal tungsten bronze-type structures.