Block copolymer nanostructures mapped by far-field optics

Nano Lett. 2009 Jun;9(6):2497-500. doi: 10.1021/nl901378e.

Abstract

We demonstrate stimulated emission depletion microscopy using opposing objective lenses to noninvasively reveal the nanoscale morphology of block copolymers in three dimensions with focused light. This is exemplified in a poly(styrene-block-2-vinylpyridine) model system in which contrast is achieved by specifically staining the vinylpyridine phase with a fluorescent dye. We image swelling induced mesopores and other convoluted structures within the bulk of samples, at scales that have so far required electron and scanning probe microscopes.

Publication types

  • Research Support, Non-U.S. Gov't