Octacyanometalate-based ferrimagnetic M(V)Mn(III) (M = Mo, W) bimetallic chain racemates with slow magnetic relaxations

Inorg Chem. 2009 Jul 6;48(13):5617-9. doi: 10.1021/ic900879d.

Abstract

Cyanide-bridged M(V)-Mn(III) (M = Mo, W) bimetallic chain complexes with racemic spatial dispositions were constructed by self-assembling [M(CN)(8)](3-) precursors and Mn(III) Schiff bases. Antiferromagnetic couplings between spin centers within a chain result in a ferrimagnetic nature, and slow magnetic relaxations are observed as well.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Hydrogen Bonding
  • Magnetics*
  • Metals / chemistry*
  • Models, Molecular
  • Molecular Structure
  • Stereoisomerism

Substances

  • Metals