Varying molecular interactions by coverage in supramolecular surface chemistry

Chem Commun (Camb). 2012 Jan 14;48(4):534-6. doi: 10.1039/c1cc14497a. Epub 2011 Nov 9.

Abstract

The possibility of modifying the intermolecular interactions of absorbed benzene-carboxylic acids from coordination to hydrogen bonding by changing their surface coverage is demonstrated through a combination of scanning tunnelling microscopy, X-ray photoemission spectroscopy and density functional theory calculations.