A highly porous metal-organic framework, constructed from a cuboctahedral super-molecular building block, with exceptionally high methane uptake

Ulrich Stoeck; Simon Krause; Volodymyr Bon; Irena Senkovska; Stefan Kaskel

doi:10.1039/c2cc34840c

A highly porous metal-organic framework, constructed from a cuboctahedral super-molecular building block, with exceptionally high methane uptake

Chem Commun (Camb). 2012 Nov 14;48(88):10841-3. doi: 10.1039/c2cc34840c.

Authors

Ulrich Stoeck¹, Simon Krause, Volodymyr Bon, Irena Senkovska, Stefan Kaskel

Affiliation

¹ Dresden University of Technology, Department of Inorganic Chemistry, Bergstrasse 66, 01069 Dresden, Germany.

PMID: 23033252
DOI: 10.1039/c2cc34840c

Abstract

A highly porous metal-organic framework Cu(2)(BBCDC) (BBCDC = 9,9'-([1,1'-b[combining low line]iphenyl]-4,4'-diyl)b[combining low line]is(9H-c[combining low line]arbazole-3,6-d[combining low line]ic[combining low line]arboxylate) (DUT-49) with a specific surface area of 5476 m(2) g(-1), a pore volume of 2.91 cm(3) g(-1), a H(2) excess uptake of 80 mg g(-1) (77 K, 50 bar), a CO(2) excess uptake of 2.01 g g(-1) (298 K, 50 bar) and an exceptionally high excess methane storage capacity of 308 mg g(-1) (298 K, 110 bar) was obtained using an extended tetratopic linker.