Phosphorescence doping in a flexible ultramicroporous framework for high and tunable oxygen sensing efficiency

Chem Commun (Camb). 2013 Aug 7;49(61):6864-6. doi: 10.1039/c3cc43461c. Epub 2013 Jun 21.

Abstract

Doping very small amounts of Ru(II) into a flexible, ultramicroporous, fluorescent Zn(II) coordination polymer produced phosphorescent materials with very high and tunable oxygen quenching efficiency; and a simple color-changing ratiometric oxygen sensor has been constructed.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Fluorescent Dyes / chemical synthesis
  • Fluorescent Dyes / chemistry*
  • Models, Molecular
  • Molecular Conformation
  • Organometallic Compounds / chemical synthesis
  • Organometallic Compounds / chemistry*
  • Oxygen / analysis*
  • Particle Size
  • Polymers / chemistry
  • Porosity
  • Ruthenium / chemistry
  • Surface Properties
  • Zinc / chemistry

Substances

  • Fluorescent Dyes
  • Organometallic Compounds
  • Polymers
  • Ruthenium
  • Zinc
  • Oxygen