Glucansucrase acceptor reactions with d-mannose

Carbohydr Res. 2014 Mar 31:387:1-3. doi: 10.1016/j.carres.2014.01.013. Epub 2014 Jan 23.

Abstract

The main acceptor product of glucansucrases with d-mannose has not previously been identified. We used glucansucrases that form water-insoluble α-d-glucans to produce increased yields of acceptor products from d-mannose, and identified the major product as 6-O-α-d-glucopyranosyl-d-mannose. Glucansucrases that synthesize insoluble α-d-glucans produced higher yields of the disaccharide compared to typical dextransucrases.

Keywords: Acceptor reactions; Dextransucrase; Glucansucrase; Mannose.

Publication types

  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Disaccharides / chemistry
  • Glucans / chemistry*
  • Glucosyltransferases / chemistry
  • Glycosyltransferases / chemistry*
  • Mannose / chemistry*
  • Molecular Structure

Substances

  • Disaccharides
  • Glucans
  • Glycosyltransferases
  • Glucosyltransferases
  • alternansucrase
  • dextransucrase
  • Mannose