CO2 as a smart gelator for Pluronic aqueous solutions

Chem Commun (Camb). 2014 Nov 25;50(91):14233-6. doi: 10.1039/c4cc06623e.

Abstract

It was found that CO2 could induce the gelation of Pluronic aqueous solutions, during which the microstructure of the solution transforms from randomly dispersed spherical micelles to cubic close packed micelles. The gelation switched by compressed CO2 has many advantages and can be applied in the synthesis of porous materials.

MeSH terms

  • Carbon Dioxide / chemistry*
  • Gels / chemistry*
  • Micelles
  • Particle Size
  • Polyethylene Glycols / chemistry*
  • Propylene Glycols / chemistry*
  • Scattering, Small Angle
  • Solutions
  • Surface Properties
  • Water / chemistry
  • X-Ray Diffraction

Substances

  • Gels
  • Micelles
  • PEO-PPO-PEO
  • Propylene Glycols
  • Solutions
  • Water
  • Carbon Dioxide
  • Polyethylene Glycols