Nanoscale interplay of strain and doping in a high-temperature superconductor

Nano Lett. 2014 Dec 10;14(12):6749-53. doi: 10.1021/nl501890k. Epub 2014 Nov 7.

Abstract

The highest-temperature superconductors are electronically inhomogeneous at the nanoscale, suggesting the existence of a local variable that could be harnessed to enhance the superconducting pairing. Here we report the relationship between local doping and local strain in the cuprate superconductor Bi(2)Sr(2)CaCu(2)O(8+x). We use scanning tunneling microscopy to discover that the crucial oxygen dopants are periodically distributed in correlation with local strain. Our picoscale investigation of the intraunit-cell positions of all oxygen dopants provides essential structural input for a complete microscopic theory.

Keywords: Bi2Sr2CaCu2O8+x; High-Tc superconductors; cuprates; scanning tunneling microscopy; strain.

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Computer Simulation
  • Copper / chemistry*
  • Elastic Modulus
  • Electric Conductivity*
  • Hot Temperature
  • Materials Testing
  • Metal Nanoparticles / chemistry*
  • Metal Nanoparticles / ultrastructure*
  • Models, Chemical*
  • Tensile Strength

Substances

  • Copper
  • cuprous oxide