Direct synthesis of a {Co₆(III)Fe₆(III)} dodecanuclear complex, revealing an unprecedented molecular structure type

Eduard N Chygorin; Vladimir N Kokozay; Irina V Omelchenko; Oleg V Shishkin; Ján Titiš; Roman Boča; Dmytro S Nesterov

doi:10.1039/c5dt01149c

Direct synthesis of a {Co₆(III)Fe₆(III)} dodecanuclear complex, revealing an unprecedented molecular structure type

Dalton Trans. 2015 Jun 28;44(24):10918-22. doi: 10.1039/c5dt01149c. Epub 2015 May 20.

Authors

Eduard N Chygorin¹, Vladimir N Kokozay, Irina V Omelchenko, Oleg V Shishkin, Ján Titiš, Roman Boča, Dmytro S Nesterov

Affiliation

¹ Department of Inorganic Chemistry, Taras Shevchenko National University, Volodymyrska str. 64/13, Kyiv 01601, Ukraine.

PMID: 25992842
DOI: 10.1039/c5dt01149c

Abstract

A novel heterometallic Co6Fe6 Schiff base complex, possessing an unprecedented {M12(μ-X)22} branched structure (according to the search via the Cambridge Structural Database), has been prepared using the "direct synthesis" approach and characterized by single crystal X-ray diffraction and magnetometry.