Osteogenic Evaluation of 3D-printed PLA scaffolds Integrated with Khellin-loaded Chitosan-Alginate Sponges for Bone Tissue Engineering

Chem Asian J. 2025 Apr 17;20(8):e202401480. doi: 10.1002/asia.202401480. Epub 2025 Feb 14.

Abstract

Bone tissue engineering (BTE) offers promising strategies for bone regeneration, yet the effective delivery of bioactive molecules remains a challenge. Khellin (KH), a plant-derived furanochromone, possesses various biological properties, though its potential in promoting osteogenesis has not been thoroughly investigated. In this study, 3D-printed polylactic acid (PLA) scaffolds were integrated with KH-loaded chitosan-alginate sponges (PLA/ALG/CS-KH) to facilitate controlled and sustained delivery of KH. Using sol-gel and freeze-drying techniques, KH was incorporated at varying concentrations (60, 70, and 80 μM) to enhance its bioavailability. Comprehensive physicochemical analyses demonstrated that KH incorporation did not alter the scaffolds' porosity, swelling capacity, protein adsorption, degradation rates, or biomineralization potential. In vitro studies revealed that the PLA/ALG/CS-KH scaffolds were biocompatible with mesenchymal stem cells and effectively promoted osteogenic differentiation, particularly at a concentration of 70 μM KH. These results suggest that PLA/ALG/CS-KH scaffolds have significant potential as osteoinductive platforms for BTE applications, providing a novel approach for enhancing bone regeneration through the sustained release of KH.

Keywords: Alginate; Chitosan; Khellin; Scaffold; bone tissue engineering.

MeSH terms

  • Alginates* / chemistry
  • Animals
  • Biocompatible Materials / chemistry
  • Biocompatible Materials / pharmacology
  • Bone Regeneration / drug effects
  • Bone and Bones
  • Cell Differentiation / drug effects
  • Chitosan* / chemistry
  • Humans
  • Mesenchymal Stem Cells / cytology
  • Mesenchymal Stem Cells / drug effects
  • Osteogenesis* / drug effects
  • Polyesters* / chemistry
  • Porosity
  • Printing, Three-Dimensional*
  • Tissue Engineering*
  • Tissue Scaffolds* / chemistry

Substances

  • poly(lactide)
  • Chitosan
  • Polyesters
  • Alginates
  • Biocompatible Materials