ROS-ATM-CHK2 axis stabilizes HIF-1α and promotes tumor angiogenesis in hypoxic microenvironment

Oncogene. 2025 Jun;44(21):1609-1619. doi: 10.1038/s41388-025-03336-w. Epub 2025 Mar 8.

Abstract

Hypoxia is an established hallmark of tumorigenesis. HIF-1α activation may be the prime driver of adaptive regulation of tumor cells reacting to hypoxic conditions of the tumor microenvironment. Here, we report a novel regulatory mechanism in charge of the fundamental stability of HIF-1α in solid tumor. Under hypoxic conditions, the checkpoint kinase CHK2 binds to HIF-1α and inhibits its ubiquitination, which is highly likely due to phosphorylation of a threonine residue (Thr645), a formerly uncharacterized site within the inhibitory domain. Meanwhile, HIF-1α phosphorylation induced by CHK2 promotes complex formation between HIF-1-α and the deubiquitination enzyme USP7, increasing stability under hypoxic conditions. This novel modification of the crosstalk between phosphorylation and ubiquitination of HIF-1α mediated by CHK2 enriches the post-translational modification spectrum of HIF-1α, thus offering novel insights into potential anti-angiogenesis therapies.

MeSH terms

  • Angiogenesis
  • Animals
  • Ataxia Telangiectasia Mutated Proteins* / genetics
  • Ataxia Telangiectasia Mutated Proteins* / metabolism
  • Cell Hypoxia
  • Cell Line, Tumor
  • Checkpoint Kinase 2* / genetics
  • Checkpoint Kinase 2* / metabolism
  • Humans
  • Hypoxia-Inducible Factor 1, alpha Subunit* / genetics
  • Hypoxia-Inducible Factor 1, alpha Subunit* / metabolism
  • Mice
  • Neovascularization, Pathologic* / genetics
  • Neovascularization, Pathologic* / metabolism
  • Neovascularization, Pathologic* / pathology
  • Phosphorylation
  • Protein Stability
  • Reactive Oxygen Species* / metabolism
  • Signal Transduction
  • Tumor Microenvironment*
  • Ubiquitination

Substances

  • Hypoxia-Inducible Factor 1, alpha Subunit
  • Checkpoint Kinase 2
  • HIF1A protein, human
  • Ataxia Telangiectasia Mutated Proteins
  • CHEK2 protein, human
  • Reactive Oxygen Species
  • ATM protein, human