Simultaneously Selective Detection of Trace Lead and Cadmium Ions by Bi-Modified Delaminated Ti3C2Tx/GCE Sensor: Optimization, Performance and Mechanism Insights

Abstract

Lead (Pb) and cadmium (Cd) ions have serious negative impacts on human health and the ecological environment due to toxicity, persistence and nonbiodegradability. Among various trace Pb and Cd ions detection technologies, electrochemical analysis is considered as one of the most promising methods. The deposition of Bi nanoparticles on delaminated Ti₃C₂T_x (DL-Ti₃C₂T_x) develops a sensor with good conductivity and performance. Square wave anodic stripping voltammetry (SWASV) technology was applied to simultaneously deposit Bi on DL-Ti₃C₂T_x/GCE and achieve the rapid detection of Pb and Cd ions. The Bi nanoparticles effectively improved the sensitivity of Bi/DL-Ti₃C₂T_x/GCE sensors to detect Pb and Cd ions. The preparation conditions of the Bi/DL-Ti₃C₂T_x/GCE were optimized, including DL-Ti₃C₂T_x droplet amount, solution pH, Bi³⁺ concentration, deposition time and deposition potential, to improve the detection ability. The Bi/DL-Ti₃C₂T_x/GCE sensor has detection limits of 1.73 and 1.06 μg/L for Pb and Cd ions, respectively (S/N > 3). This electrochemical sensor is easy, sensitive and selective to apply in actual water samples for trace Pb and Cd ions detection.

Keywords: Bi nanoparticles; actual water; sensitivity; square wave anodic stripping voltammetry.