In vitro assessment of berberine-loaded carboxymethyl chitosan hydrogel: A promising antimicrobial candidate for S. aureus-induced bovine mastitis treatment

PLoS One. 2025 Jun 27;20(6):e0326574. doi: 10.1371/journal.pone.0326574. eCollection 2025.

Abstract

Bovine mastitis poses significant challenges to the global dairy industry, leading to substantial economic losses and public health concerns. Staphylococcus aureus, a prevalent causative agent of bovine mastitis, depends on effective adhesion and biofilm formation to establish infections. Berberine (BER), a naturally occurring phytochemical, demonstrates broad-spectrum antibacterial activity but suffers from poor bioavailability. This study developed a composite berberine-carboxymethyl chitosan/sodium alginate hydrogel to address these limitations. The hydrogel was characterized using scanning electron microscopy, Fourier-transform infrared spectroscopy, and X-ray diffraction. In vitro assessments revealed that the BER hydrogel eradicated S. aureus biofilms (42% eradication at 156.26 μg/mL), inhibited bacterial adhesion, and reduced inflammatory cytokines (IL-6 and TNF-α) in S. aureus-infected MAC-T cells, with compliant biosafety biocompatibility (hemolysis rate <5%) and sustained drug release (100% over 6 h), though pH-dependent release kinetics necessitate microenvironment-specific formulation refinement. In conclusion, the BER hydrogel represents a potential therapeutic candidate for S. aureus-induced bovine mastitis.

MeSH terms

  • Alginates / chemistry
  • Animals
  • Anti-Bacterial Agents* / chemistry
  • Anti-Bacterial Agents* / pharmacology
  • Bacterial Adhesion / drug effects
  • Berberine* / administration & dosage
  • Berberine* / chemistry
  • Berberine* / pharmacology
  • Biofilms / drug effects
  • Cattle
  • Chitosan* / analogs & derivatives
  • Chitosan* / chemistry
  • Drug Liberation
  • Female
  • Hydrogels* / chemistry
  • Mastitis, Bovine* / drug therapy
  • Mastitis, Bovine* / microbiology
  • Staphylococcal Infections* / drug therapy
  • Staphylococcal Infections* / microbiology
  • Staphylococcal Infections* / veterinary
  • Staphylococcus aureus* / drug effects
  • Staphylococcus aureus* / physiology

Substances

  • Chitosan
  • Berberine
  • Hydrogels
  • carboxymethyl-chitosan
  • Anti-Bacterial Agents
  • Alginates